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Diaquabis(malato-κ2O1,O2)copper(II)

✍ Scribed by Zhang, Xin-Yan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
117 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C 6 H 5 O 5 ) 2 (H 2 O) 2 ], the Cu II atom, located on an inversion center, is coordinated by four O atoms from two malate ligands forming the equatorial plane and two water molecules in axial positions, resulting in an elongated octahedral geometry. The structure of this compound has been reported previously [Polyanskaya et al. (1982). Zh. Strukt. Khim. 23,[117][118], but the quality of the refinement has been improved. The packing is governed by intermolecular O-HÁ Á ÁO hydrogen bonds, forming an intricate three-dimensional network.

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