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Diaqua­bis(vanillinato-κ2O,O′)manganese(II)

✍ Scribed by Gao, Jian ;Liu, Yu

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
163 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Mn(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], the Mn II atom is located on a twofold axis and is coordinated by two vanillinate anions and two water molecules in a distorted octahedral geometry. The vanillinate ligand chelates to the Mn II atom through its methoxy and hydroxy O atoms, with greatly differing Mn-O bond distances [2.3506 ( 14) and 2.0901 (12) A ˚].

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