In the title complex, [Mn(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], the Mn II atom is located on a twofold axis and is coordinated by two vanillinate anions and two water molecules in a distorted octahedral geometry. The vanillinate ligand chelates to the Mn II atom through its methoxy and hydroxy O atoms, with
Diaquabis(1,2-di-4-pyridylethane-κN)bis(2-nitrobenzoate-κO)manganese(II)
✍ Scribed by Zhang, Li-Li ;Zhang, Wei-Guang ;Zhong, Hui ;Zhang, Yu
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 194 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Di-l-acetato-j 4 O:O 0 0 0 -bis[bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )manganese(II)] bis(perchlorate)
The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.
In red crystal of the title compound, [Mn(NCS) 2 (C 6 H 8 -N 2 O 2 ) 2 (H 2 O) 2 ]Á2H 2 O, the Mn II atom lies on an inversion centre and assumes a distorted octahedral coordination geometry. Hydrogen bonds consolidate the crystal structure.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.031 wR factor = 0.082 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.