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Diaqua­bis(2,3-dimethyl­pyrazine 1,4-dioxide-κO)bis­(thio­cyanato-κN)manganese(II) dihydrate

✍ Scribed by Wu, Chang-Ju ;Zhang, Xia ;Liu, Lian-Dong ;Shi, Jing-Min

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
108 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In red crystal of the title compound, [Mn(NCS) 2 (C 6 H 8 -N 2 O 2 ) 2 (H 2 O) 2 ]Á2H 2 O, the Mn II atom lies on an inversion centre and assumes a distorted octahedral coordination geometry. Hydrogen bonds consolidate the crystal structure.

📜 SIMILAR VOLUMES

Tetra­aqua­bis(thio­cyanato-κN)zinc(II)
Tetra­aqua­bis(thio­cyanato-κN)zinc(II) bis­(2-methyl­pyrazine 1,4-dioxide)
✍ Xu, Wen ;Shi, Jing-Min ;Zhang, Xia 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 115 KB

In the title compound, [Zn(NCS) 2 (H 2 O) 4 ]Á2C 5 H 6 N 2 O 2 , the six-coordinated Zn II atom lies on a special position of site symmetry 2/m. The methylpyrazine dioxide molecule lies on a mirror plane and links with the Zn II complex via O-HÁ Á ÁO hydrogen bonding.

Diaqua­bis[4-(dimethyl­amino)benzoato-κO
Diaqua­bis[4-(dimethyl­amino)benzoato-κO](nicotinamide-κN1)cobalt(II) dihydrate
✍ Hökelek, Tuncer ;Necefoğlu, Hacali 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

The title complex, [Co(C 9 H 10 NO 2 ) 2 (C 6 H 6 N 2 O) 2 (H 2 O) 2 ]Á-2H 2 O, is monomeric with the Co atom situated on a crystallographic center of inversion. It contains two 4-(dimethylamino)benzoate (DMAB) and two nicotinamide (NA) ligands, and two coordinated and two uncoordinated water molecu

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)manganese(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.