catena-Poly[[[aquacopper(II)
Diaquabis[(E)-2-(4-oxopentan-2-ylideneamino)benzoato-κO]dipyridinemanganese(II)
✍ Scribed by Shi, Shao-Min ;Hu, Zong-Qiu
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 354 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Mn(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], the Mn II atom is located on a twofold axis and is coordinated by two vanillinate anions and two water molecules in a distorted octahedral geometry. The vanillinate ligand chelates to the Mn II atom through its methoxy and hydroxy O atoms, with
The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.
The title Mn^II^ complex, [Mn(C~7~H~5~O~3~)~2~(C~10~H~8~N~2~)~2~], has twofold symmetry, with the Mn^II^ atom located on a twofold axis. Two 4-hydroxybenzoate anions and two 2,2′-bipyridine coordinate to the Mn^II^ atom which has a distorted octahedral geometry. Hydrogen bonding between the carboxyl
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.