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Diaqua­bis[(E)-2-(4-oxopentan-2-ylideneamino)­benzoato-κO]dipyridine­manganese(II)

✍ Scribed by Shi, Shao-Min ;Hu, Zong-Qiu


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
354 KB
Volume
63
Category
Article
ISSN
1600-5368

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In the title complex, [Mn(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], the Mn II atom is located on a twofold axis and is coordinated by two vanillinate anions and two water molecules in a distorted octahedral geometry. The vanillinate ligand chelates to the Mn II atom through its methoxy and hydroxy O atoms, with

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The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.

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The title Mn^II^ complex, [Mn(C~7~H~5~O~3~)~2~(C~10~H~8~N~2~)~2~], has twofold symmetry, with the Mn^II^ atom located on a twofold axis. Two 4-hydroxybenzoate anions and two 2,2′-bipyridine coordinate to the Mn^II^ atom which has a distorted octahedral geometry. Hydrogen bonding between the carboxyl

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The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.