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Bis(2,2′-bipyridine-κ2N,N′)bis­(4-hydroxy­benzoato-κO)manganese(II)

✍ Scribed by Hu, Zi-Qiang ;Wu, Lian-Bin ;Lai, Guo-Qiao


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
260 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title Mn^II^ complex, [Mn(C~7~H~5~O~3~)~2~(C~10~H~8~N~2~)~2~], has twofold symmetry, with the Mn^II^ atom located on a twofold axis. Two 4-hydroxybenzoate anions and two 2,2′-bipyridine coordinate to the Mn^II^ atom which has a distorted octahedral geometry. Hydrogen bonding between the carboxylate and hydroxyl groups forms a sheet perpendicular to the a axis.


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