Di-l-acetato-j 4 O:O 0 0 0 -bis[bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )manganese(II)] bis(perchlorate)
Bis(2,2′-bipyridine-κ2N,N′)bis(4-hydroxybenzoato-κO)manganese(II)
✍ Scribed by Hu, Zi-Qiang ;Wu, Lian-Bin ;Lai, Guo-Qiao
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 260 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title Mn^II^ complex, [Mn(C~7~H~5~O~3~)~2~(C~10~H~8~N~2~)~2~], has twofold symmetry, with the Mn^II^ atom located on a twofold axis. Two 4-hydroxybenzoate anions and two 2,2′-bipyridine coordinate to the Mn^II^ atom which has a distorted octahedral geometry. Hydrogen bonding between the carboxylate and hydroxyl groups forms a sheet perpendicular to the a axis.
📜 SIMILAR VOLUMES
Bis(benzoato-j 2 O,O 0 0 0 )(2,2 0 0 0 -bipyridyl-j 2 N,N 0 0 0 )zinc(II)
Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1