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Diaqua­bis(3-hydroxy­pyridine N-oxide)dithio­cyanato­cobalt(II)

✍ Scribed by Shi, Jing-Min ;Xu, Hai-Yan ;Liu, Lian-Dong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
121 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title mononuclear complex, [Co(NCS)~2~(C~5~H~5~NO~2~)~2~(H~2~O)~2~], the six-coordinated Co^II^ atom lies on an inversion center. In the crystal structure, intermolecular O—H...O (H...O = 1.85–2.01 Å) and O—H...S (H...S = 2.40 Å) hydrogen bonds link molecules into a three-dimensional network.

📜 SIMILAR VOLUMES

Diaqua­bis[4-(3-pyrid­yl)-1H-1,2,4-triaz
Diaqua­bis[4-(3-pyrid­yl)-1H-1,2,4-triazole]dithio­cyanato­manganese(II)
✍ Li, Hui ;Li, Chang-Jin ;Hu, Zhi-Qiang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 132 KB

Single-crystal X-ray study T = 294 K Mean (C-C) = 0.005 A R factor = 0.045 wR factor = 0.120 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.