The title compound, [Cu(CH~3~CO~2~)~2~(C~9~H~7~N~3~O)~2~(H~2~O)], is a mononuclear complex in which the Cu^II^ atom assumes a square-pyramidal coordination geometry. The Cu atom and the aqua O atom lie on a crystallographic twofold rotation axis. In the crystal structure, there are hydrogen bonds an
Tetrakis[3-(pyrazin-2-yloxy)pyridine-κN]dithiocyanatomanganese(II)
✍ Scribed by Zhao, Hong-Yan ;Shi, Jing-Min ;Liu, Lian-Dong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 129 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In red crystal of the title compound, [Mn(NCS) 2 (C 6 H 8 -N 2 O 2 ) 2 (H 2 O) 2 ]Á2H 2 O, the Mn II atom lies on an inversion centre and assumes a distorted octahedral coordination geometry. Hydrogen bonds consolidate the crystal structure.
The asymmetric unit of the title compound [Cu~8~ ^I^Cu~2~ ^II^(CN)~4~(NCS)~8~(C~6~H~8~N~2~)~7~], consists of six crystallographically independent Cu atoms, four thiocyanate anions and two cyanide anions, as well as four 2,6-dimethylpyrazine ligands. Two of the six Cu atoms and one of the four 2,6-di