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Diaquabis{2,4-dibromo-6-[2-(isopropylammonio)ethyliminomethyl]phenolato}nickel(II) dichloride hemihydrate

✍ Scribed by Tang, Chun-Bao

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
587 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Ni(C~12~H~16~Br~2~N~2~O~2~)~2~(H~2~O)~2~]Cl~2~·0.5H~2~O, consists of a centrosymmetric mononuclear nickel(II) complex cation, two symmetry-related chloride anions and a half-occupancy water molecule. The Ni atom, lying on an inversion centre, is six-coordinated by two phenol O atoms, two imine N atoms from two Schiff base ligands, and the O atoms from two water molecules, forming an octahedral geometry. Adjacent molecules are linked through intermolecular hydrogen bonds, forming chains running along the b axis.

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