Bis[2,4-dibromo-6-(cyclopropyliminomethyl)phenolato]nickel(II)
✍ Scribed by Li, Li-Zhong ;Wang, Li-Hua
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 372 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Ni(C 10 H 8 Br 2 NO) 2 ], is a mononuclear nickel(II) complex. The Ni II atom, located on an inversion centre, exhibits a square-planar coordination geometry. The metal atom is bonded to two phenolate O atoms and two imine N atoms from two Schiff base ligands.
📜 SIMILAR VOLUMES
In the mononuclear title complex, [Zn(C 10 H 8 Cl 2 NO) 2 ],the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands.
The asymmetric unit of the title compound, C 10 H 9 Br 2 NO, consists of two molecules. In both molecules, the benzene and cyclopropyl rings are nearly perpendicular, with dihedral angles of 85.8 (4) and 75.5 (4) . In the crystal structure, there are no obviously short intermolecular contacts. Each
In the centrosymmetric binuclear title compound, [Cu 2 (C 13 H 11 Br 2 N 2 O) 2 (NO 3 ) 2 ], each Cu II atom is five-coordinated by two phenolate O atoms, one nitrate O atom, one pyridine N atom and one amine N atom in a distorted trigonal-bipyramidal CuO 3 N 2 environment. The CuÁ Á ÁCu separation
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.019 A Ê R factor = 0.055 wR factor = 0.159 Data-to-parameter ratio = 13.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.