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2,4-Dibromo-6-(cyclopropyliminomethyl)phenol

✍ Scribed by Yang, De-Suo


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
580 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The asymmetric unit of the title compound, C 10 H 9 Br 2 NO, consists of two molecules. In both molecules, the benzene and cyclopropyl rings are nearly perpendicular, with dihedral angles of 85.8 (4) and 75.5 (4) . In the crystal structure, there are no obviously short intermolecular contacts. Each molecule has an intramolecular O-HÁ Á ÁN hydrogen bond.


πŸ“œ SIMILAR VOLUMES


Bis[2,4-dibromo-6-(cyclopropyliminomethy
✍ Li, Li-Zhong ;Wang, Li-Hua πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 372 KB

The title compound, [Ni(C 10 H 8 Br 2 NO) 2 ], is a mononuclear nickel(II) complex. The Ni II atom, located on an inversion centre, exhibits a square-planar coordination geometry. The metal atom is bonded to two phenolate O atoms and two imine N atoms from two Schiff base ligands.

2,4-Dibromo-6-(4-iodophenyliminomethyl)p
✍ Guo, Ming-Lin ;Nong, Xiu-Ru ;Yin, Heng πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 300 KB

The molecular skeleton of the title Schiff base compound, C 13 H 8 Br 2 INO, is essentially planar due to an intramolecular N-HÁ Á ÁO hydrogen bond; the two aromatic rings make a dihedral angle of 4.4 (5) . The crystal packing exhibits short intermolecular IÁ Á ÁBr contacts of 3.7226 (16) A ˚.

2,4-Dibromo-6-(2-hydroxyΒ­ethylΒ­iminiomet
✍ Sun, Yu-Xi ;Zhang, Ran ;Tian, Lai-Jin ;Xu, Lai-Xiang ;Sun, Shan-Li πŸ“‚ Article πŸ“… 2006 πŸ› International Union of Crystallography 🌐 English βš– 359 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.005 A R factor = 0.024 wR factor = 0.055 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.