2,4-Dibromo-6-(cyclopropyliminomethyl)phenol
β Scribed by Yang, De-Suo
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 580 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
β¦ Synopsis
The asymmetric unit of the title compound, C 10 H 9 Br 2 NO, consists of two molecules. In both molecules, the benzene and cyclopropyl rings are nearly perpendicular, with dihedral angles of 85.8 (4) and 75.5 (4) . In the crystal structure, there are no obviously short intermolecular contacts. Each molecule has an intramolecular O-HΓ Γ ΓN hydrogen bond.
π SIMILAR VOLUMES
The title compound, [Ni(C 10 H 8 Br 2 NO) 2 ], is a mononuclear nickel(II) complex. The Ni II atom, located on an inversion centre, exhibits a square-planar coordination geometry. The metal atom is bonded to two phenolate O atoms and two imine N atoms from two Schiff base ligands.
The molecular skeleton of the title Schiff base compound, C 13 H 8 Br 2 INO, is essentially planar due to an intramolecular N-HΓ Γ ΓO hydrogen bond; the two aromatic rings make a dihedral angle of 4.4 (5) . The crystal packing exhibits short intermolecular IΓ Γ ΓBr contacts of 3.7226 (16) A Λ.
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.005 A R factor = 0.024 wR factor = 0.055 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.