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Bis[2,4-dibromo-6-(cyclopropyliminomethyl)phenolato]zinc(II)

✍ Scribed by Yuan, Wen-Bing ;Xu, Hong-Wu ;Li, Jin-Xia ;Liu, Min ;Zhang, Qi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
379 KB
Volume
63
Category
Article
ISSN
1600-5368

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The title compound, [Ni(C 10 H 8 Br 2 NO) 2 ], is a mononuclear nickel(II) complex. The Ni II atom, located on an inversion centre, exhibits a square-planar coordination geometry. The metal atom is bonded to two phenolate O atoms and two imine N atoms from two Schiff base ligands.

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In the mononuclear title complex, [Zn(C 10 H 8 Cl 2 NO) 2 ],the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands.

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Bis­[2-(cyclo­propyl­imino­methyl)­phenolato]­zinc(II)
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.019 A Ê R factor = 0.055 wR factor = 0.159 Data-to-parameter ratio = 13.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis[4-bromo-2-(cyclo­propyl­imino­meth­y
Bis[4-bromo-2-(cyclo­propyl­imino­meth­yl)phenolato]zinc(II)
✍ You, Zhong-Lu 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 100 KB

In the mononuclear title complex, [Zn(C 10 H 9 BrNO) 2 ], the Zn II atom is four-coordinated by two imine N and two phenolate O atoms from two Schiff base ligands in a distorted tetrahedral geometry.

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2,4-Dibromo-6-(cyclopropyliminomethyl)phenol
✍ Yang, De-Suo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 580 KB

The asymmetric unit of the title compound, C 10 H 9 Br 2 NO, consists of two molecules. In both molecules, the benzene and cyclopropyl rings are nearly perpendicular, with dihedral angles of 85.8 (4) and 75.5 (4) . In the crystal structure, there are no obviously short intermolecular contacts. Each