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Diaquabis{2-[2-(isopropylammonio)ethyliminomethyl]-6-methoxyphenolato}nickel(II) dinitrate dihydrate

✍ Scribed by Wang, Ying-Zhen ;Li, Lan-Lan ;Su, Yong-Qing ;Li, Cong

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 486 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807055092

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✦ Synopsis

The title compound, [Ni(C 13 H 20 N 2 O 2 ) 2 (H 2 O) 2 ](NO 3 ) 2 Á2H 2 O, consists of a mononuclear nickel(II) complex, two nitrate anions and two solvent water molecules. The Ni atom lies on an inversion centre and is chelated by the phenolic O and imine N atoms from two Schiff base ligands, and coordinated by the O atoms from two water molecules, giving a slightly distorted octahedral geometry. Within the crystal structure, the components form chains parallel to the a axis by intermolecular N-HÁ Á ÁO, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds.

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