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Diaquabis(5-n-butylpyridine-2-carboxylato-κ2N,O)nickel(II) dihydrate

✍ Scribed by Qin, Liang ;Guo, Hai-Fu ;Li, Xiang ;Ma, De-Yun ;Song, Wen-Dong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
585 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The metal atom of the title compound, [Ni(C~10~H~13~NO~2~)~2~(H~2~O)~2~]·2H~2~O, lies on an inversion center; it is N,O-chelated by the alkyl-substituted 2-pyridylcarboxylate group, and two water molecules complete the octahedral environment. The coordinated and solvent water molecules engage in hydrogen bonding with the acceptor O atom of the carboxylate group to furnish a two-dimensional network motif. Three atoms of the butyl group are disordered, with refined site occupancies of 0.681 (8):0.319 (8).

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