Diaquabis(quinoline-2-carboxylato-κ2N,O)magnesium(II) dihydrate methanol disolvate
✍ Scribed by Tai, Xi-Shi ;Yin, Jie ;Hao, Ming-Yang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 538 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the title compound, [Mg(C 10 H 6 NO 2 ) 2 (H 2 O) 2 ]Á2H 2 OÁ2CH 3 OH, the Mg atom (site symmetry 1) adopts a slightly distorted trans-MgN 2 O 4 octahedral geometry arising from two N,O-bidentate quinaldine ligands and two water molecules. The structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
The metal atom of the title compound, [Ni(C~10~H~13~NO~2~)~2~(H~2~O)~2~]·2H~2~O, lies on an inversion center; it is __N__,__O__-chelated by the alkyl-substituted 2-pyridylcarboxylate group, and two water molecules complete the octahedral environment. The coordinated and solvent water molecules engag
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.004 A Ê R factor = 0.038 wR factor = 0.111 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.