In the title mononuclear nickel(II) complex, [Ni(C 14 H 18 -NO 2 ) 2 ], the Ni II atom is four-coordinated in a square-planar geometry by two phenolate O atoms and two imine N atoms from two Schiff base ligands. The Ni atom lies on a centre of inversion. ## metal-organic papers Acta Cryst. (2006)
Bis[6-(cyclopentyliminomethyl)-2-methoxyphenolato]nickel(II)
✍ Scribed by Zhao, Xiao-Fan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 166 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of the title mononuclear compound, [Ni(C~13~H~16~NO~2~)~2~], possesses crystallographic inversion symmetry. The Ni atom, lying on the inversion centre, is four-coordinated in a square-planar geometry by two Schiff base ligands.
📜 SIMILAR VOLUMES
In the mononuclear title complex, [Zn(C 10 H 8 Cl 2 NO) 2 ],the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands.
The title complex, [Cu(C 13 H 16 NO 2 ) 2 ], is a mononuclear copper(II) complex. The Cu atom is located on a crystallographic inversion centre and is coordinated by two O and two N atoms from two Schiff base ligands, forming a squareplanar geometry.
In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C 20 H 25 N 2 O) 2 ], the Ni II ion has octahedral geometry and is coordinated by two O atoms and four N atoms from two Schiff bases.
In the mononuclear title compound, [Co(C 13 H 15 ClNO) 2 ], the Co atom is four-coordinated by two N atoms and two O atoms from two Schiff base ligands in a slightly distorted tetrahedral geometry.