In the mononuclear copper(II) compound, [Cu(C 13 H 17 Cl 2 -N 2 O)(N 3 )], the Cu II ion is four-coordinated by one imine N, one amine N, and one phenolate O atom of the Schiff base ligand, and by one terminal N atom of an azide anion, forming a distorted square-planar coordination.
✦ LIBER ✦
Azido{2,4-dibromo-6-[2-(diethylamino)ethyliminomethyl]phenolato}copper(II)
✍ Scribed by Li, Kun ;Zhang, Hong ;Wang, Xiao-Na ;Peng, Jin-Yong ;Diao, Yun-Peng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 551 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Cu(C 11 H 13 Cl 2 N 2 O)(N 3 )] n , is an azidebridged polymeric copper(II) complex. The Cu atom is pentacoordinated by one O and two N atoms of the Schiff base ligand and two bridging N atoms from two azide groups, forming a trigonal-bipyramidal geometry. The structure is furth