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catena-Poly[[{2,4-dichloro-6-[2-(ethylamino)ethyliminomethyl]phenolato}copper(II)]-μ-azido]

✍ Scribed by Diao, Yun-Peng ;Shu, Xiao-Hong ;Zhang, Bao-Jing ;Zhen, Yu-Hong ;Kang, Ting-Guo

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
662 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(C 11 H 13 Cl 2 N 2 O)(N 3 )] n , is an azidebridged polymeric copper(II) complex. The Cu atom is pentacoordinated by one O and two N atoms of the Schiff base ligand and two bridging N atoms from two azide groups, forming a trigonal-bipyramidal geometry. The structure is further stabilized by an N-HÁ Á ÁO hydrogen bond.

📜 SIMILAR VOLUMES

Azido­{2,4-dichloro-6-[2-(diethyl­amino)
Azido­{2,4-dichloro-6-[2-(diethyl­amino)ethyl­imino­meth­yl]phenolato}copper(II)
✍ Wei, Yi-Jun ;Wang, Feng-Wu 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 286 KB

In the mononuclear copper(II) compound, [Cu(C 13 H 17 Cl 2 -N 2 O)(N 3 )], the Cu II ion is four-coordinated by one imine N, one amine N, and one phenolate O atom of the Schiff base ligand, and by one terminal N atom of an azide anion, forming a distorted square-planar coordination.

Dichloro­{2,4-dichloro-6-[2-(isopropyl­a
Dichloro­{2,4-dichloro-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}zinc(II)
✍ Hu, Yang-Jian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A R factor = 0.044 wR factor = 0.100 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.