d-Glucose and d-mannose-based metabolic probes. Part 3: Synthesis of specifically deuterated d-glucose, d-mannose, and 2-deoxy-d-glucose
β Scribed by Fokt, Izabela; Skora, Stanislaw; Conrad, Charles; Madden, Timothy; Emmett, Mark; Priebe, Waldemar
- Book ID
- 120317465
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 592 KB
- Volume
- 368
- Category
- Article
- ISSN
- 0008-6215
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Condensation of Z-deoxy-~-ribose with nitromethane gave, after deionization, a syrupy mixture of epimeric l-nitro-1,3-dideoxy-hexitols. Acid hydrolysis under Nef reaction conditions produced a mixture of 3-deoxy-~-glucose and 3-deoxy-m mannose, separable by cellulose chromatography or fractional cry
## Abstract A convenient method for the synthesis of ^18^Fβ2βdeoxyβ2βfluoroβDβglucose (4) and ^18^Fβ2βdeoxyβ2βfluoroβDβmannose (8) by the direct fluorination of 3,4,6βtriβ0βacetylβDβglucal with ^18^FβF~2~ is described. ^14^Cβ2βdeoxyβ2βfluoroβDβglucose has been synthesized from ^14^Cβ3,4,6βtriβ0βace
A modification of Keston's glucose oxidase method for D-glucose analysis is described. The glucose oxidase-peroxidase reaction was carried out in phosphate buffer, pH 5.9 at 45 Β°, for 30 minutes. A clear stable color was developed by addition of sulfuric acid to a final concentration of 30 per cent.