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Coupled Cluster and Second-Order Møller−Plesset Perturbation Studies of the Mechanism of the Gas-Phase Atom−Radical Reaction of Atomic Hydrogen with CF 2 Radical

✍ Scribed by Francisco, Joseph S.


Book ID
126777510
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
70 KB
Volume
104
Category
Article
ISSN
1089-5639

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✍ R. A. Taccone; O. Salinovich; E. H. Staricco 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 573 KB

The following gas-phase reactions: (1) ( 2 ) were studied by the competitive method with CF,I as the source of radicals. The kinetic parameters obtained in the temperature range 533-613 K and 503-613 K respectively for chlorine atom transfer reactions are given by: log hl/h,"(cm3 mol-" s -") = 16