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Theoretical investigation of the gas-phase reactions of CF2ClC(O)OCH3with the hydroxyl radical and the chlorine atom at 298 K

✍ Scribed by Bhupesh Kumar Mishra, Arup Kumar Chakrabartty…

Book ID
120923199
Publisher
Springer-Verlag
Year
2013
Tongue
English
Weight
307 KB
Volume
19
Category
Article
ISSN
1610-2940

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## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d

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The kinetics of the gas-phase reaction of C1 atoms with CF31 have been studied relative to the reaction of C1 atoms with CH4 over the temperature range 271-363 K. Using k(C1 + CH4) = 9.6 X exp(-2680/RT) cm3 molecule-' s-', we derive k(C1 + CF3I) = 6.25 X lo-'' exp(-2970/RT) in which E , has units of