## Abstract Rate constants for the gasโphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d
Kinetics, mechanism and thermochemistry of the gas phase reactions of CF3CH2OCH2CF3 with OH radicals: A theoretical study
โ Scribed by Lily, Makroni; Mishra, Bhupesh Kumar; Chandra, Asit K.
- Book ID
- 122221730
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 943 KB
- Volume
- 161
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical
CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 ฯณ 356 K u