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Theoretical studies on the reactions of CHF2CF2OCH3/CH2FCF2OCH3 with OH radicals

✍ Scribed by Wang, Li; Zhao, Jianxiang; He, Hongqing; Zhang, Jinglai


Book ID
121890051
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
958 KB
Volume
149
Category
Article
ISSN
0022-1139

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πŸ“œ SIMILAR VOLUMES


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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical

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## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d

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## Abstract A dual‐level direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFE‐245fa2; HFE‐245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m