## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical
Theoretical studies on the reactions of CHF2CF2OCH3/CH2FCF2OCH3 with OH radicals
β Scribed by Wang, Li; Zhao, Jianxiang; He, Hongqing; Zhang, Jinglai
- Book ID
- 121890051
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 958 KB
- Volume
- 149
- Category
- Article
- ISSN
- 0022-1139
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π SIMILAR VOLUMES
## Abstract Rate constants for the gasβphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d
## Abstract A dualβlevel direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFEβ245fa2; HFEβ245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m