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Rate Constants for the Reactions of OH Radicals with CH 3 OCF 2 CHF 2 , CHF 2 OCH 2 CF 2 CHF 2 , CHF 2 OCH 2 CF 2 CF 3 , and CF 3 CH 2 OCF 2 CHF 2 over the Temperature Range 250−430 K

✍ Scribed by Tokuhashi, Kazuaki; Takahashi, Akifumi; Kaise, Masahiro; Kondo, Shigeo; Sekiya, Akira; Yamashita, Shiro; Ito, Haruaki

Book ID
127072777
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
73 KB
Volume
104
Category
Article
ISSN
1089-5639

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📜 SIMILAR VOLUMES

Kinetics for the gas-phase reactions of
Kinetics for the gas-phase reactions of OH radicals with the hydrofluoroethers CH2FCF2OCHF2, CHF2CF2OCH2CF3, CF3CHFCF2OCH2CF3, and CF3CHFCF2OCH2CF2CHF2 at 268–308 K
✍ L. Chen; S. Kutsuna; K. Tokuhashi; A. Sekiya; K. Takeuchi; T. Ibusuki 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 122 KB 👁 2 views

## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical

Rate constants for the reactions of the
Rate constants for the reactions of the hydroxyl radical with CHF2CF2CF2CHF2 and CF3CHFCHFCF2CF3
✍ Z. Zhang; R.D. Saini; M.J. Kurylo; R.E. Huie 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 383 KB

Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21