Partially halogenated hydrocarbons CHFClCF3, CF3CH3, CF3CHFCHF2, CF3CH2CF3, CHF2CF2CH2F, CF3CH2CHF2, CF3OCHF2: critical temperature, refractive indices, surface tension and estimates of liquid, vapor and critical densities
✍ Scribed by James W Schmidt; Ernesto Carrillo-Nava; Michael R Moldover
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 947 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0378-3812
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21