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Atmospheric Chemistry of CF 3 CH 2 OCH 2 CF 3 : UV Spectra and Kinetic Data for CF 3 CH(•)OCH 2 CF 3 and CF 3 CH(OO•)OCH 2 CF 3 Radicals and Atmospheric Fate of CF 3 CH(O•)OCH 2 CF 3 Radicals

✍ Scribed by Wallington, T. J.; Guschin, A.; Stein, T. N. N.; Platz, J.; Sehested, J.; Christensen, L. K.; Nielsen, O. J.


Book ID
121347905
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
149 KB
Volume
102
Category
Article
ISSN
1089-5639

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## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d