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Theoretical study on dynamics of the gas phase reactions of CF3CF2CH2OCHF2 with OH radicals

✍ Scribed by Wang, Li; Zhang, Ting; Wen, Jinmiao; He, Hongqing; Zhang, Jinglai


Book ID
126642004
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
562 KB
Volume
168
Category
Article
ISSN
0022-1139

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πŸ“œ SIMILAR VOLUMES


Theoretical study of the reactions CF3CH
✍ Lei Yang; Jing-Yao Liu; Li Wang; Hong-Qing He; Ying Wang; Ze-Sheng Li πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 603 KB

## Abstract A dual‐level direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFE‐245fa2; HFE‐245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m

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## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical