Theoretical study on dynamics of the gas phase reactions of CF3CF2CH2OCHF2 with OH radicals
β Scribed by Wang, Li; Zhang, Ting; Wen, Jinmiao; He, Hongqing; Zhang, Jinglai
- Book ID
- 126642004
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 562 KB
- Volume
- 168
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A dualβlevel direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFEβ245fa2; HFEβ245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m
## Abstract Rate constants were determined for the reactions of OH radicals with the hydrofluoroethers (HFEs) CH~2~FCF~2~OCHF~2~(__k__~1~), CHF~2~CF~2~OCH~2~CF~3~ (__k__~2~), CF~3~CHFCF~2~OCH~2~CF~3~(__k__~3~), and CF~3~CHFCF~2~OCH~2~CF~2~CHF~2~(__k__~4~) by using a relative rate method. OH radical