Kinetics of the gas phase reactions of chlorine atoms and OH radicals with CF3CBrCH2 and CF3CF2CBrCH2
β Scribed by M.P. Sulbaek Andersen; M.D. Hurley; T.J. Wallington
- Book ID
- 108108975
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 228 KB
- Volume
- 482
- Category
- Article
- ISSN
- 0009-2614
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CF 3 CF 2 CH 2 OH is a new chlorofluorocarbon (CFC) alternative. However, there are few data about its atmospheric fate. The kinetics of its atmospheric oxidation, the OH radical reaction of CF 3 CF 2 CH 2 OH, has been investigated in a 2-liter Pyrex reactor in the temperature range of 298 Ο³ 356 K u
## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClο£ΎCCl~2~ (__k__~1~), CF~3~CClο£ΎCClCF~3~ (__k__~2~) and CF~3~CFο£ΎCFCF~3~ (__k__~3~). Experiments were carried out at (298Β±2) K and atmospheric pressure using ultrapure nitr