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Atmospheric Chemistry of CF 3 CHCH 2 and C 4 F 9 CHCH 2 : Products of the Gas-Phase Reactions with Cl Atoms and OH Radicals

✍ Scribed by Nakayama, T.; Takahashi, K.; Matsumi, Y.; Toft, A.; Sulbaek Andersen, M. P.; Nielsen, O. J.; Waterland, R. L.; Buck, R. C.; Hurley, M. D.; Wallington, T. J.


Book ID
126202494
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
150 KB
Volume
111
Category
Article
ISSN
1089-5639

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Substituent effects on the disproportion
✍ John D. Ferguson; Bert E. Holmes πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 184 KB

## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 Β± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 Β± 0.03 when the H is removed from the CH~3~ position in the reaction with t