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Atmospheric Chemistry of 4:2 Fluorotelomer Iodide ( n -C 4 F 9 CH 2 CH 2 I): Kinetics and Products of Photolysis and Reaction with OH Radicals and Cl Atoms

✍ Scribed by Young, Cora J.; Hurley, Michael D.; Wallington, Timothy J.; Mabury, Scott A.


Book ID
127390834
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
568 KB
Volume
112
Category
Article
ISSN
1089-5639

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Atmospheric chemistry of CH2FOCH2F: Reac
✍ M. Goto; M. Kawasaki; T. J. Wallington; M. D. Hurley; A. P. Sharratt πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 185 KB

## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ— 10^βˆ’13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ— 10^βˆ’15^ (in un