๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Competing modes of decomposition of triarylsulfonium alkoxides

โœ Scribed by Catherine Chen Lai; William E. McEwen

Book ID
104248080
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
224 KB
Volume
12
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

The reaction of a triarylsulfonium halide with a sodium alkoxide in a eolution in the corresponding alcohol at en elevated temperature produces a mixture of aramatlc hydrocarbon, alkyl aryl ether, diary1 sulfide and aldol resin (or a ketone if the alkoxlde ie derived from a secondary alcohol).i,2 Frequently, a small amount of biaryl is also produced. We have

๐Ÿ“œ SIMILAR VOLUMES

Decomposition of triarylsulfonium alkoxi
Decomposition of triarylsulfonium alkoxides
โœ Jerome W. Knapczyk; Gayl H. Wiegand; William E. McEwen ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 278 KB

In a previous cozmmmication (1) we have suggested that the mechanism of pyrolysis of triarylsulf~ium halides to give diary1 sulfides snd the corresponding aryl halides involves the additlcn of the halide ion to the sulfur atom of the sulfonium cation and subsequent intramolecular collapse of the add

Thermal Decomposition of Aluminum Alkoxi
Thermal Decomposition of Aluminum Alkoxides 1
โœ Shulman, Garson P.; Trusty, Monty; Vickers, J. H. ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 555 KB