๐”– Bobbio Scriptorium
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Competing modes of decomposition of diaryliodonium alkoxides

โœ Scribed by William E. McEwen; Jacek J. Lubinkowski; Jerome W. Knapczyk


Book ID
104245109
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
226 KB
Volume
13
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Competing modes of decomposition of tria
โœ Catherine Chen Lai; William E. McEwen ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

The reaction of a triarylsulfonium halide with a sodium alkoxide in a eolution in the corresponding alcohol at en elevated temperature produces a mixture of aramatlc hydrocarbon, alkyl aryl ether, diary1 sulfide and aldol resin (or a ketone if the alkoxlde ie derived from a secondary alcohol).i,2 Fr

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In a previous cozmmmication (1) we have suggested that the mechanism of pyrolysis of triarylsulf~ium halides to give diary1 sulfides snd the corresponding aryl halides involves the additlcn of the halide ion to the sulfur atom of the sulfonium cation and subsequent intramolecular collapse of the add

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โœ Shulman, Garson P.; Trusty, Monty; Vickers, J. H. ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 555 KB
Acid generation in the thermal decomposi
โœ William E. McEwen; John W. DeMassa ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 523 KB

Diphenyliodonium tetrafluoroborate and diphenyliodonium hexafluorophosphate have been found to generate u p to two equivalents of hydrogen fluoride per equivalent of the iodonium salt by pyrolysis at 239ยฐC in the neat state and at 150ยฐC in the presence of anisole or nitrobenzene. The formation of hy