Intrinsic fragmentation modes of primary alkoxides
β Scribed by D.A. Evans; D.J. Baillargeon
- Book ID
- 104237311
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 223 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The reaction of a triarylsulfonium halide with a sodium alkoxide in a eolution in the corresponding alcohol at en elevated temperature produces a mixture of aramatlc hydrocarbon, alkyl aryl ether, diary1 sulfide and aldol resin (or a ketone if the alkoxlde ie derived from a secondary alcohol).i,2 Fr
## Abstract Thermolysis of the potassium 2βsubstituted bicyclo [2.2.2]octβ5βenβ2βalkoxides derived from alcohols **2β17** at 90β120Β° in hexamethylphosphoric triamide affords unsaturated ketones resulting from allylic bond cleavage. The mechanistic and synthetic aspects of this anionic fragmentation