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Decomposition of triarylsulfonium alkoxides

โœ Scribed by Jerome W. Knapczyk; Gayl H. Wiegand; William E. McEwen

Book ID
104240511
Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
278 KB
Volume
6
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

In a previous cozmmmication (1) we have suggested that the mechanism of pyrolysis of triarylsulf~ium halides to give diary1 sulfides snd the corresponding aryl halides involves the additlcn of the halide ion to the sulfur atom of the sulfonium cation and subsequent intramolecular collapse of the adduct. We have now carried out a study of the decanposition of triarylsulfoniwn alkoxides, and the results are summarized in Table .

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