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Reactions of triarylsulfonium salts with sodium alkoxides

โœ Scribed by Knapczyk, Jerome W.; Lai, Catherine C.; McEwen, William E.; Calderon, Jose L.; Lubinkowski, Jacek J.


Book ID
126162283
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
606 KB
Volume
97
Category
Article
ISSN
0002-7863

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Reactions of alkoxides with alkoxysulfon
โœ Carl R. Johnson; W. Gary Phillips ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

The reaction of alkoxides with simple alkoxysulfonium salts such as dimethyl methoxysulfonium fluoroborate (I) proceeds via rapid inter-changes of the alkoxy group followed by base-catalyzed elimination to provide carbonyl compounds. This procedure focuses attention concurrently on two types of reac