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Reactions of alkoxides with alkoxysulfonium salts

✍ Scribed by Carl R. Johnson; W. Gary Phillips

Publisher: Elsevier Science
Year: 1965
Tongue: French
Weight: 173 KB
Volume: 6
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90161-8

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✦ Synopsis

The reaction of alkoxides with simple alkoxysulfonium salts such as dimethyl methoxysulfonium fluoroborate (I) proceeds via rapid inter-changes of the alkoxy group followed by base-catalyzed elimination to provide carbonyl compounds. This procedure focuses attention concurrently on two types of reactions which have previously been observed.

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