ChemInform Abstract: Reaction of Chloroalkylbenzothiazoles with Alkoxides.
β Scribed by S. FLORIO; V. CAPRIATI; G. COLLI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Cleavage of the C-S bond of predominantly with carbon-oxygen dibenzothiophene 5,5-dioxide (1) by alkoxide ions proceeds bond formation, in contrast to the observation of predominant \_\_ \_ sulfur-oxygen bond formation in the reaction of 1 with hydroxide. The esr spectrum of the radical anion of 1 h
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The reaction of alkoxides with simple alkoxysulfonium salts such as dimethyl methoxysulfonium fluoroborate (I) proceeds via rapid inter-changes of the alkoxy group followed by base-catalyzed elimination to provide carbonyl compounds. This procedure focuses attention concurrently on two types of reac