Benzoato[hydridotris(3,5-methylphenylpyrazolyl)borato-j 3 N,N 0 0 0 ,N 0 0 00 0 0 ]zinc(II)
Cocrystal of (2-guanidinobenzimidazole-κ2N,N′)[hydridotris(3,5-methylphenylpyrazolyl)borato-κ3N,N′,N′′]cobalt(II) perchlorate and (2-guanidinobenzimidazolato-κ2N,N′)[hydridotris(3,5-methylphenylpyrazolyl)borato-κ3N,N′,N′′]cobalt(II) methanol solvate monohydrate
✍ Scribed by He, Hong-Shan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 182 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Zn(C~30~H~28~BN~6~)(C~4~H~3~N~2~O~3~)]·CH~3~OH, the Zn^II^ atom is coordinated in a tetrahedral geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by one O atom from a barbiturate anion.
Reaction of potassium hydridotris(5-methyl-3-phenylpyrazoly)borate with copper(II) acetate in methanol at room temperature gives the title compound, [Cu(C 30 H 28 BN 6 )-(C 2 H 3 O 2 )]. The Cu atom is five-coordinated by three N atoms from pyrazolyl groups and two O atoms from the acetate ligand.
In the title complex {alternative name: (2,2 0 -bipyridine- the V IV atom is six-coordinated by three O atoms and three N atoms in a distorted octahedral configuration. In the crystal structure, the combination of intermolecular hydrogen-bonding (O-HÁ Á ÁO) and -stacking interactions creates a thre
Hydridotris(pyrazol-1-yl)borato-j 3 N,-N 0 0 0 ,N 0 0 00 0 0 ][5,10,15,20-tetrakis(4-methylphenyl)porphyrinato-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]samarium(III) toluene 1.75-solvate