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[Hydridotris(5-methyl-3-phenyl­pyrazol-1-yl)borato-κ3N2,N2′,N2′′](1H-imidazole-4-carboxyl­ato-κ2N,O)zinc(II) methanol solvate

✍ Scribed by He, Hong-Shan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
225 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

(Barbiturato-κO)[hydridotris(5-methyl-3-
(Barbiturato-κO)[hydridotris(5-methyl-3-phenyl-1-pyrazol­yl)borato-κ3N2,N2′,N2′′]­zinc(II) methanol solvate
✍ He, Hongshan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 357 KB

In the title compound, [Zn(C~30~H~28~BN~6~)(C~4~H~3~N~2~O~3~)]·CH~3~OH, the Zn^II^ atom is coordinated in a tetrahedral geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by one O atom from a barbiturate anion.

Acetato[hydridotris(5-methyl-3-phenylpyr
Acetato[hydridotris(5-methyl-3-phenylpyrazol-1-yl-κN2)borato]copper(II)
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

Reaction of potassium hydridotris(5-methyl-3-phenylpyrazoly)borate with copper(II) acetate in methanol at room temperature gives the title compound, [Cu(C 30 H 28 BN 6 )-(C 2 H 3 O 2 )]. The Cu atom is five-coordinated by three N atoms from pyrazolyl groups and two O atoms from the acetate ligand.

Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]
Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]zinc(II) methanol solvate
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

In the title complex, [Zn(C 18 H 14 N 4 O 2 )]ÁCH 3 OH, two anionic 2-(1H-imidazol-2-yl)phenolate bidentate ligands coordinate through the phenolate O and imidazolyl N atoms to the central Zn II atom to give a four-coordinate tetrahedral geometry.