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Acetato[hydridotris(5-methyl-3-phenylpyrazol-1-yl-κN2)borato]copper(II)

✍ Scribed by He, Hong-Shan

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 174 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806029187

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✦ Synopsis

Reaction of potassium hydridotris(5-methyl-3-phenylpyrazoly)borate with copper(II) acetate in methanol at room temperature gives the title compound, [Cu(C 30 H 28 BN 6 )-(C 2 H 3 O 2 )]. The Cu atom is five-coordinated by three N atoms from pyrazolyl groups and two O atoms from the acetate ligand.

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In the title complex, [CuCl~2~(C~31~H~28~N~6~)]·0.5C~2~H~3~N, the Cu^2+^ atom is coordinated in a distorted square-pyramidal geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by two chloride anions.

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.006 A Ê Disorder in main residue R factor = 0.052 wR factor = 0.156 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.