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Bis(2,2′-bipyridine-κN,N′){[5-(carboxy­methyl­sulfanyl)-1,3,4-thia­diazol-2-ylsulfanyl]acetato-κO}copper(II) [5-(carboxy­methyl­sulfan­yl)-1,3,4-thia­diazol-2-ylsulfan­yl]acetate dihydrate

✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Zhao, Hui ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
338 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.006 A Ê Disorder in main residue R factor = 0.052 wR factor = 0.156 Data-to-parameter ratio = 16.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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✍ Chang, Jiu-Li ;Wang, Li-Ya ;Jiang, Kai 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 339 KB

In the title complex, [Hg(NO 3 ) 2 (C 10 H 15 N 3 OS) 2 ], the Hg II ion (site symmetry 1) adopts a grossly distorted octahedral geometry by chelation of two neutral Him-thz ligands [Himthz is 2-(2 0 -thiazole)-4,4,5,5-tetramethyldihydro-1H-imidazolyl-1-hydroxy] through their thiazole N atoms [Hg-N