In the title compound, [Zn(C~30~H~28~BN~6~)(C~4~H~3~N~2~O~3~)]·CH~3~OH, the Zn^II^ atom is coordinated in a tetrahedral geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by one O atom from a barbiturate anion.
[Hydridotris(pyrazol-1-yl)borato-κ3N,N′,N′′][5,10,15,20-tetrakis(4-methylphenyl)porphyrinato-κ4N,N′,N′′,N′′′]samarium(III) toluene 1.75-solvate
✍ Scribed by He, Hongshan ;He, Guishan ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 1002 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Hydridotris(pyrazol-1-yl)borato-j 3 N,-N 0 0 0 ,N 0 0 00 0 0 ][5,10,15,20-tetrakis(4-methylphenyl)porphyrinato-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]samarium(III) toluene 1.75-solvate
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The structure of the title compound, [Zn(C 92 H 60 N 4 )-(C 2 H 3 N)]ÁC 2 H 3 N, shows relatively small saddle-type distortion with ruf¯ing, compared to other dodecaphenylporphyrin complexes.
mer-Bis(2,3-dimethyl-5-oxo-1-phenyl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethylthiosemicarbazonato-j 3 S,N,O)cobalt(III) tetrafluoroborate Jesu ´s Valde ´s-Martı ´nez, a