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Claisen rearrangement of allylfluorovinyl ethers
✍ Scribed by Frédérique Tellier; Max Audouin; Monique Baudry; Raymond Sauvêtre
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 251 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
One pot synthesis of cr-fluoro P-substituted y-unsaturated acids via a diastereoselective Claisen rearrangement of allylfluorovinyl ethers is described.
📜 SIMILAR VOLUMES
Claisen Rearrangement of Allylfluorovinyl Ethers. -Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides α-fluoro-β-substituted γ-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity
A one-pot synthesis of α-bromo β-substituted γ-unsaturated acids via a diastereoselective Claisen rearrangement of allyl