Studies in claisen rearrangements claisen rearrangement of bispropargyl ethers
β Scribed by K.K. Balasubramanian; B. Venugopalan
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 249 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
One pot synthesis of cr-fluoro P-substituted y-unsaturated acids via a diastereoselective Claisen rearrangement of allylfluorovinyl ethers is described.
A one-pot synthesis of Ξ±-bromo Ξ²-substituted Ξ³-unsaturated acids via a diastereoselective Claisen rearrangement of allyl
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Claisen Rearrangement of Allylfluorovinyl Ethers. -Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides Ξ±-fluoro-Ξ²-substituted Ξ³-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity