Claisen Rearrangement of Allylfluorovinyl Ethers. -Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides α-fluoro-β-substituted γ-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity
✦ LIBER ✦
ChemInform Abstract: Claisen Rearrangement of Allylfluorovinyl Ethers.
✍ Scribed by F. TELLIER; M. AUDOUIN; M. BAUDRY; R. SAUVETRE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract The presence of the free hydroxy‐group in the chiral catalyst is crucial.