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ChemInform Abstract: Claisen Rearrangement of Allyl Bromofluorovinyl Ethers.

✍ Scribed by Frederique Tellier; Max Audouin; Monique Baudry; Raymond Sauvetre


Publisher
John Wiley and Sons
Year
2001
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Claisen Rearrangement of Allyl Bromofluo
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A one-pot synthesis of Ξ±-bromo Ξ²-substituted Ξ³-unsaturated acids via a diastereoselective Claisen rearrangement of allyl

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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Claisen Rearrangement of Allylfluorovinyl Ethers. -Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides Ξ±-fluoro-Ξ²-substituted Ξ³-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity