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ChemInform Abstract: Claisen Rearrangement of Allylfluorovinyl Ethers.
โ Scribed by Frederique Tellier; Max Audouin; Monique Baudry; Raymond Sauvetre
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Claisen Rearrangement of Allylfluorovinyl Ethers.
-Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides ฮฑ-fluoro-ฮฒ-substituted ฮณ-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity.
๐ SIMILAR VOLUMES
A one-pot synthesis of ฮฑ-bromo ฮฒ-substituted ฮณ-unsaturated acids via a diastereoselective Claisen rearrangement of allyl
## Abstract The presence of the free hydroxyโgroup in the chiral catalyst is crucial.