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ChemInform Abstract: Gosteli—Claisen Rearrangement of Propargyl Vinyl Ethers: Cascading Molecular Rearrangements.

✍ Scribed by Annika Gille; Julia Rehbein; Martin Hiersemann

Publisher
John Wiley and Sons
Year
2011
Weight
38 KB
Volume
42
Category
Article
ISSN
0931-7597

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Claisen Rearrangement of Allylfluorovinyl Ethers. -Claisen rearrangement of allyl fluorovinyl ethers, obtained by attack of allyl alkoxide on trifluorovinylsilane (II), provides α-fluoro-β-substituted γ-unsaturated acid derivatives (III) (10 examples) with moderate to good anti-diastereoselectivity