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Chloro­(1-isopropyl­idene-4-methyl-3-thio­semicarbazidato-κ2N3,S)diphenyl­tin(IV)

✍ Scribed by Swesi, Abdurazag T. ;Farina, Yang ;Venkatraman, Ramaiyer ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
231 KB
Volume
62
Category
Article
ISSN
1600-5368

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Chloro­(1-isopropyl­idene-4-methyl-3-thi
✍ Swesi, Abdurazaq T. ;Farina, Yang ;Yamin, Bohari M. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 244 KB

In the title compound, [Sn(CH 3 ) 2 (C 5 H 10 N 3 S)Cl], the 1isopropylidene-4-methyl-3-thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is s

(Acetone 4-phenyl­thio­semicarbazonato-κ
✍ Swesi, Abdurazag T. ;Farina, Yang ;Venkatraman, Ramaiyer ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 150 KB

The Sn IV atom in the title compound, [Sn(C 6 H 5 ) 2 -(C 10 H 12 N 3 S)Cl]ÁC 2 H 5 OH, exists in a cis-trigonal-bipyramidal geometry. The Cl and imino N atoms occupy the axial sites.

Di-μ-chloro-bis{chloro­[3,5-di­methyl-1-
✍ Radosavljević Evans, Ivana ;Mészáros Szécsényi, Katalin ;Leovac, Vukadin M. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom