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Chloro­(1-isopropyl­idene-4-methyl-3-thio­semicarbazidato-κ2N3,S)dimethyl­tin(IV)

✍ Scribed by Swesi, Abdurazaq T. ;Farina, Yang ;Yamin, Bohari M.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
244 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Sn(CH 3 ) 2 (C 5 H 10 N 3 S)Cl], the 1isopropylidene-4-methyl-3-thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-HÁ Á ÁN and intermolecular N-HÁ Á ÁS hydrogen bonds. The latter link the molecules into dimers.

📜 SIMILAR VOLUMES

Di-μ-chloro-bis{chloro­[3,5-di­methyl-1-
Di-μ-chloro-bis{chloro­[3,5-di­methyl-1-(thio­carbamoyl)­pyrazole-κ2N2,S]­cadmium(II)}
✍ Radosavljević Evans, Ivana ;Mészáros Szécsényi, Katalin ;Leovac, Vukadin M. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

The crystal structure of the title compound, [Cd 2 Cl 4 -(C 6 H 9 N 3 S) 2 ], has been determined. The compound is isomorphous with the previously reported Cu II and Co II complexes. It is centrosymmetric and contains binuclear molecular units with five-coordinate Cd atoms, doubly bridged by Cl atom